Lithium fluoride formed in situ is trapped by [TiF3(C5Me5)]2: an equilibrium with cleavage of a Ti–F–Ti bond and a model compound for molecular lithium fluoride

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Alojz Demsar, Andrej Pevec, Ljubo Golič, Saša Petriček, Andrej Petrič, Alojz Demsar, Andrej Pevec, Saša Petriček, Andrej Petrič and Herbert W. Roesky


Abstract

Synthesis and structure of [{(C5Me5)TiF3}4(LiF)] and its solution equilibrium involving cleavage of a titanium–fluorine–titanium bond is reported.


References

  1. A. F. Janzen, Coord. Chem. Rev., 1994, 130, 355 CrossRef CAS.
  2. R. O. Duthaler and A. Hafner, Angew. Chem., 1997, 109, 43 CrossRef; Angew. Chem., Int. Ed. Engl., 1997, 36, 43 Search PubMed.
  3. D. R. Gauthier, Jr. and E. M. Carreira, Angew. Chem., 1996, 108, 2521 CrossRef; Angew. Chem., Int. Ed. Engl., 1996, 35, 2363 Search PubMed.
  4. F. S. Mair and R. Snaith, in Encyclopaedia of Inorganic Chemistry, ed. R. B. King, Wiley, Chichester, UK, 1994, vol. 1, 35 Search PubMed.
  5. A. G. Avent, W.-Y. Chen, C. Eaborn, I. B. Gorell, B. B. Hitchcock and J. D. Smith, Organometallics, 1996, 15, 4343 CrossRef CAS.
  6. A. F. Wells, Structural Inorganic Chemistry, Clarendon Press, Oxford, UK, 4th edn., 1975, p. 375 Search PubMed.
  7. A. Pevec, A. Demsar, V. Gramlich, S. Petricek and H. W. Roesky, J. Chem. Soc., Dalton Trans., 1997, 2215 RSC.
  8. H. W. Roesky, M. Sotoodeh and M. Noltemeyer, Angew. Chem., 1992, 104, 869 CAS; Angew. Chem., Int. Ed. Engl., 1992, 31, 864 Search PubMed.
  9. Xtal3.2 Reference Manual, ed. S. R. Hall, H. D. Flack and J. M. Steward, Universities of Western Australia, Geneva and Maryland, 1992 Search PubMed.
  10. M. Sootodeh, I. Leichtweis, H. W. Roesky, M. Noltemeyer and H.-G. Schmidt, Chem. Ber., 1993, 126, 913 CrossRef CAS.
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