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DOI: 10.1039/A800213D (Paper) Reference Section for: Chem. Commun., 1998, 591-592

Binding of the uranyl moiety by an Amavadin-style complex; synthesis and characterisation of [{UO2(H2O)3}{Δ-V(hida)2}·2H2O]n

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Robert E. Berry, Paul D. Smith, Spencer M. Harben, Madeleine Helliwell, David Collison and C. David Garner

Abstract

[Δ-V(hida)2]2– (H3hida = N-hydroxyiminodiacetic acid) and UO22+ form the solid [{UO2(H2O)3}{Δ-V(hida)2}·2H2O]n which is comprised of left-handed helical arrays, linked by H-bonding networks, in which the VIV is eight-coordinate and the UVI seven-coordinate.

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