Direct synthesis of organochlorosilanes by the reaction of metallic silicon with hydrogen chloride and alkene/alkyne

Abstract

Organosilicon compounds were directly synthesized from metallic silicon, alkene/alkyne and HCl, EtHSiCl₂ being obtained with 47% selectivity from Si, C₂H₄ and HCl at 513 K, and CH₂[double bond, length half m-dash]CHSiHCl₂ and EtHSiCl₂ with 39 and 23% selectivity, respectively, when C₂H₂ was used in place of C₂H₄.

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