High catalytic efficiency of transition metal complexes encapsulated in a cubic mesoporous phase

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M. Eswaramoorthy


Abstract

Copper(II) acetate dimer and [MnII(bipy)2]2+ encapsulated in cubic Al-MCM-48 show high catalytic activity in the oxidation of phenol to catechol by oxygen activation, and of styrene to styrene oxide by singlet oxygen, respectively.


References

  1. D. R. Corbin and N. Herron, J. Mol. Catal., 1994, 86, 343 CrossRef CAS.
  2. L. M. Sayre and D. V. Nadkarni, J. Am. Chem. Soc., 1994, 116, 3157 CrossRef CAS.
  3. R. Robert and P. Ratnasamy, J. Mol. Catal., 1995, 100, 93 Search PubMed.
  4. P. P. Knops-Gerrits, D. D. Vos, F. Thibault-Starzyk and P. A. Jacobs, Nature, 1994, 369, 543 CrossRef CAS.
  5. S. S. Kim, W. Zhang and T. J. Pinnavaia, Catal. Lett., 1997, 43, 149 CrossRef CAS.
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