Synthesis of Si and Ti-Si-MCM-48 mesoporous materials with controlled pore sizes in the absence of polar organic additives and alkali metal ions

(Note: The full text of this document is currently only available in the PDF Version )

Avelino Corma and Qiubin Kan


Abstract

A new route for the synthesis of Si- and Si-Ti-MCM-48 has been developed which allows these materials to be obtained without using polar organic additives and alkali metal ions; this procedure not only produces more active and selective Ti-MCM-48 oxidation catalysts than those reported before, but also permits the synthesis of MCM-48 with controlled pore diameters.


References

  1. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli and J. S. Beck, Nature, 1992, 359, 710 CrossRef CAS.
  2. C. Y. Chen, S. L. Burkett, H. X. Li and M. E. Davis, Microporous Mater., 1993, 2, 27 CrossRef CAS.
  3. A. Corma, V. Fornes, M. T. Navarro and J. Perez-Pariente, J. Catal., 1994, 148, 569 CrossRef CAS.
  4. A. Corma, M. T. Navarro and J. Perez-Pariente, J. Chem. Soc., Chem. Commun., 1994, 147 RSC; T. Blasco, A. Corma, M. T. Navarro and J. P. Pariente, J. Catal., 1995, 156, 65 CrossRef CAS.
  5. K. M. Reddy, I. L. Moudrakouski and A. Sayari, J. Chem. Soc., Chem. Commun., 1995, 973 RSC.
  6. F. Rey, G. Sankar, T. Maschmeyer, J. M. Thomas and R. G. Bell, Top. Catal., 1996, 3, 121 CAS.
  7. A. Corma, Chem. Rev., 1997, 97, 2373 CrossRef CAS.
  8. A. Monnier, F. Schuth, Q. Huo, D. Kumar, D. Margolese, R. S. Maxwell, G. D. Stucky, M. Krishnamurty, P. Petroff, A. Firouzi, M. Janicke and B. F. Chmelka, Science, 1993, 261, 1299 CrossRef CAS.
  9. J. C. Vartuli, K. D. Schmitt, C. T. Kresge, W. J. Roth, M. E. Leonowicz, S. B. McCullen, S. D. Hellring, J. S. Beck, J. L. Schlenker, D. H. Olson and E. W. Sheppard, Chem. Mater., 1994, 6, 2317 CrossRef CAS.
  10. Q. Huo, D. Y. Margolese and G. D. Stucky, Chem. Mater., 1996, 8, 1147 CrossRef CAS.
  11. K. W. Gallis and C. C. Landry, Chem. Mater., 1997, 9, 2035 CrossRef CAS.
  12. D. Zhao and D. Goldfarb, J. Chem. Soc., Chem. Commun., 1995, 875 RSC.
  13. M. Morey, A. Davidson and G. Stucky, Microporous Mater., 1996, 6, 99 CrossRef CAS.
  14. W. Zhang and T. J. Pinnavaia, Catal. Lett., 1966, 38, 261 CrossRef CAS.
  15. C. B. Khouw and M. E. Davis, J. Catal., 1995, 151, 77 CrossRef CAS.
  16. M. A. Camblor, A. Corma and J. Pérez-Pariente, Zeolites, 1993, 13, 82 CrossRef CAS.
  17. K. A. Koyano and t. Tatsumi, Chem. Commun., 1996, 145 RSC.
  18. A. Corma, Q. Kan, M. T. Navarro, J. Perez-Pariente and F. Rey, Chem. Mater., 1997, 9, 2123 CrossRef CAS.
  19. J. Chavrolin and J. F. Srdoc, J. Phys., 1987, 48, 189 Search PubMed.
  20. S. M. Grunner, J. Phys. Chem., 1989, 93, 7562 CrossRef.
  21. G. D. Stucky, A. Monnier, F. Schüth, Q. Huo, D. Margolese, D. Kumar, M. Krishnamurty, P. Petroff, A. Firouzi, M. Janicke and B. F. Chmelka, Mol. Cryst. Liq. Cryst., 1994, 240, 187 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.