Versatile pentadentate 1,5-bis(salicylideneamino)pentan-3-ol type ligands yield novel tri- and tetra-manganese(II) complexes: structure and properties

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Lutz Stelzig, Benoît Chansou, Jean-Pierre Tuchagues, Lutz Stelzig and Alexander Steiner


Abstract

Novel manganese–oxygen cores observed in trinuclear [MnII3(L3)22-OAc)]Na and tetranuclear [MnII2L33-OMe)(MeOH)]2 complexes [H3L3 = 1,5-bis(3-Cl,5-NO2-salicylideneamino)pentan-3-ol] illustrate the coordination versatility of the 1,5-bis(salicylideneamino)pentan-3-ol type of trianionic pentadentate Schiff bases.


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