View PDF Version
 
DOI: 10.1039/A708943K (Paper) Reference Section for: Chem. Commun., 1998, 595-596

X-Ray crystal structure of {Cu[1,2-bis(4-pyridyl)ethane]2(NO3)2}n: the first example of a coordination polymer that exhibits the NbO 3D network architecture†

(Note: The full text of this document is currently only available in the PDF Version )

K. Nicole Power, Tracy L. Hennigar and Michael J. Zaworotko

Abstract

The coordination polymer {Cu[1,2-bis(4-pyridyl)ethane]2-(NO3)2}n does not exist as a square grid network, rather it is the first example of a twofold NbO type 3D network. A twofold level of interpenetration does not preclude the presence of 11 × 11 Å channels which contain benzene and methanol guest molecules.

References

  1. D. Venkataraman, G. B. Gardner, S. Lee and J. S. Moore, J. Am. Chem. Soc., 1995, 117, 11 600 CrossRef.
  2. O. M. Yaghi, G. Li and H. Li, Nature, 1995, 378, 703 CrossRef CAS.
  3. S. Subramanian and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1994, 35, 2127.
  4. M. Fujita, Y. J. Kwon, O. Sasaki, K. Yamaguchi and K. Ogura, J. Am. Chem. Soc., 1995, 117, 7287 CrossRef CAS.
  5. G. A. Doyle, D. M. L. Goodgame, S. P. W. Hill and D. J. Williams, J. Chem. Soc., Chem. Commun., 1993, 207 RSC.
  6. P. Losier and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1996, 35, 2779 CrossRef CAS.
  7. T. Hennigar, D. C. MacQuarrie, P. Losier, R. D. Rogers and M. J. Zaworotko, Angew. Chem., Int. Ed. Engl., 1997, 36, 972 CrossRef CAS.
  8. F. Robinson and M. J. Zaworotko, Chem. Commun., 1995, 2413 RSC.
  9. O. Yaghi and H. Li, J. Am. Chem. Soc., 1996, 118, 295 CrossRef CAS.
  10. K. N. Power, T. L. Hennigar and M. J. Zaworotko, New J. Chem., in press Search PubMed.
  11. T. Iwamoto, in Inclusion Compounds, ed. J. L. Atwood, J. E. D. Davies and D. D. MacNicol, Academic Press, London, vol. 1, 1984, ch. 2, pp. 29–57 Search PubMed.
  12. R. W. Gable, B. F. Hoskins and R. Robson, J. Chem. Soc., Chem. Commun., 1990, 1677 RSC.
  13. M. Fujita, Y. J. Kwon, S. Washizu and K. Ogura, J. Am. Chem. Soc., 1994, 116, 1151 CrossRef CAS.
  14. J. L. Atwood, T. L. Hennigar, C. M. Hogg, K. T. Holman, P. Losier, L. R. MacGillivray, K. N. Power, R. D. Rogers and M. J. Zaworotko, unpublished work.
  15. J. Lu, T. Paliwals, S. C. Lim, C. Yu, T. Niu and A. J. Jacobsen, Inorg. Chem., 1997, 36, 923 CrossRef CAS.
  16. A. F. Wells, Structural Inorganic Chemistry, Clarendon Press, Oxford, 4th edn., 1975 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.