Direct conversion of perfluoroalkanes and perfluoroarenes to perfluoro Grignard reagents

(Note: The full text of this document is currently only available in the PDF Version )

Christopher M. Beck, You-Jung Park and Robert H. Crabtree


Abstract

Magnesium anthracene selectively reduces C6F12 or C6F6 and CF3C6F11 or CF3C6F5 to C6F5MgF and CF3C6F4MgF, respectively


References

  1. (a) B. Bogdanovic, N. Janke, H. Kinzelmann, K. Seevogel and J. Treber, Chem. Ber., 1990, 123, 1529 CAS; (b) B. Bagdanovic, S. Liao, R. Mynott, K. Schlichte and U. Westeppe, Chem. Ber., 1984, 117, 1378 CrossRef.
  2. (a) M. Gallagher, S. Harvey, C. Raton and R. Sue, J. Chem. Soc., Chem. Commun., 1988, 289 RSC; (b) B. Bogdanovic, Acc. Chem. Res., 1988, 21, 261 CrossRef CAS; (c) S. Harvey and C. Raston, J. Chem. Soc., Chem. Commun., 1988, 652 RSC; (d) T. Hudlicky, M. Natchus and G. Sinai-Zingde, J. Org. Chem., 1987, 52, 4644 CrossRef CAS.
  3. W. Respess and C. Tamborski, J. Organomet. Chem., 1969, 18, 263 CrossRef CAS.
  4. W. Respess, J. Ward and C. Tambroski, J. Organomet. Chem., 1969, 19, 191 CrossRef CAS.
  5. J. Kiplinger, T. Richmond and C. Osterberg, Chem. Rev., 1994, 94, 373 CrossRef CAS , and references within B. Bennett, R. Harrison and T. Richmond, J. Am. Chem. Soc., 1994, 116, 11 165 Search PubMed; J. Kiplinger and T. Richmond, J. Am. Chem. Soc., 1996, 118, 1805 CrossRef CAS; Chem. Commun., 1996, 1115 CrossRef CAS.
  6. J. Marsella, A. Gilicinski, A. Coughlin and G. Pez, J. Org. Chem., 1992, 57, 2856 CrossRef CAS; A. Oku., J. Nishimura, S. Nakagawa and K. Yamada, Nippon Kagaku Kaishi, 1985, 10, 1985; Chem. Abstr., 1986, 105, 97074z Search PubMed.
  7. C. Tamborski and E. Soloski, J. Org. Chem., 1966, 31, 746 CAS.
  8. E. C. Ashby and D. Al-Fekri, J. Organomet. Chem., 1990, 390, 275 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.