Ligand and H/D exchange of Mn(H2O)62+ and Cu(OH)(H2O)4+ in the gas phase

(Note: The full text of this document is currently only available in the PDF Version )

Steen Brøndsted Nielsen, Steen Brøndsted Nielsen and Gustav Bojesen


Abstract

When ligand exchange of aqua complexes in the gas phase is examined by reaction with D2O it is not accompanied by H/D exchange.


References

  1. J. Burgess, Metal ions in solution, Ellis Horwood, Chichester, 1978 Search PubMed.
  2. A. T. Blades, P. Jayaweera, M. G. Ikonomou and P. Kebarle, J. Chem. Phys., 1990, 92, 5900 CrossRef CAS.
  3. Y. D. Hill, B. S. Freiser and C. W. Bauschlicher, J. Am. Chem. Soc., 1991, 113, 1507 CrossRef CAS.
  4. U. N. Andersen and G. Bojesen, Int. J. Mass Spectrom. Ion Process, 1996, 153, 1 CrossRef CAS.
  5. The experiments were carried out with a Finnigan TSQ700 tripelquadrupole instrument in which the collision region is in fact an octapole. The complexes were generated by electrospray ionization from 0.20 mM aqueous solutions of appropriate salts, and the ion–molecule reactions were conducted as described in ref. 4.
  6. K. M. Ervin and P. B. Armentrout, J. Chem. Phys., 1985, 83, 166 CrossRef CAS.
  7. N. N. Dookeran and A. G. Harrison, J. Mass Spectrom., 1995, 30, 666 CAS.
  8. J. A. Stone, Org. Mass Spectrom., 1993, 28, 1119 CAS.
  9. N. N. Dookeran and A. G. Harrison, J. Am. Soc. Mass Spectrom., 1994, 6, 19 CrossRef.
  10. A. Ranasinghe, R. G. Cooks and S. K. Sethi, Org. Mass Spectrom., 1992, 27, 77 CAS.
  11. S. B. Nielsen and G. Bojesen, unpublished work.
  12. R. Tonkyn and J. C. Weisshaar, J. Am. Chem. Soc., 1986, 108, 7128 CrossRef CAS.
  13. L. M. Roth and B. S. Freiser, Mass Spectrom. Rev., 1991, 10, 303 CrossRef CAS.
  14. S. D. Price, M. Manning and S. R. Leone, J. Am. Chem. Soc., 1994, 116, 8673 CrossRef CAS.
  15. T. J. Swift and T. A. Stephenson, Inorg. Chem., 1966, 5, 1100 CrossRef CAS.
  16. R. Åkesson, L. G. M. Pettersson, M. Sandström and U. Wahlgren, J. Am. Chem. Soc., 1994, 116, 8705 CrossRef.
  17. A. K. Katz, J. P. Glusker, S. A. Beebe and C. W. Bock, J. Am. Chem. Soc., 1996, 118, 5752 CrossRef CAS.
  18. F. P. Rotzinger, J. Am. Chem. Soc., 1997, 119, 5230 CrossRef CAS.
  19. E. D. Glendening and D. Feller, J. Phys. Chem., 1996, 100, 4790 CrossRef CAS.
  20. T. J. Swift and R. E. Connick, J. Chem. Phys., 1962, 37, 307 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.