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DOI: 10.1039/A708083B (Paper) Reference Section for: Chem. Commun., 1998, 261-262

Synthesis and structure of [{(ButO)2Sb3(µ-NCy)3(µ3-NCy)}K·η6-C6H5Me]; a sandwich complex containing a unique SbIIInido cage anion (Cy = cyclohexyl, C6H11)

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Michael A. Beswick, Nick Choi, Alexander D. Hopkins, Mary McPartlin, Michael A. Paver and Dominic S. Wright

Abstract

Reaction of the terminal NMe2 groups of the spiro antimony(III) imido anion [{(Me2N)Sb(µ-NCy)}2Sb]– with ButOH results in major rearrangement in the Sb–N framework as witnessed in the structure of the sandwich complex [{(ButO)2Sb3(µ-NCy)3(µ3-NCy)}K·η6-C6H5Me] 1, containing the novel nido cage anion [(ButO)2Sb3(µ-NCy)3(µ3-NCy)]–.

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