Extended rim redox active tris-metallodioxolene derivatives of cyclotricatechylene

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D. Scott Bohle and Daniel Stasko


Abstract

Triple metallation of cyclotricatechylene (CTC) results in new cavitands with significantly extended rims and three reversible redox couples as determined by single-crystal X-ray diffraction and electrochemistry.


References

  1. J. L. Atwood, M. J. Barnes, M. G. Gardiner and C. L. Raston, Chem. Commun., 1996, 1449 RSC.
  2. R. J. Blanch, M. Williams, G. D. Fallon, M. G. Gardiner, R. Kaddour and C. L. Raston, Angew. Chem., Int. Ed. Engl., 1997, 36, 504 CrossRef CAS.
  3. D. J. Cram, J. Weiss, R. C. Helgeson, C. B. Knobler, A. E. Dorigo and K. N. Houk, J. Chem. Soc., Chem. Commun., 1988, 407 RSC.
  4. J. L. Atwood, K. T. Holman and J. W. Steed, Chem. Commun., 1996, 1401 RSC.
  5. K. T. Holman, J. W. Steed and J. L. Atwood, Angew. Chem., Int. Ed. Engl., 1997, 36, 1736 CrossRef CAS.
  6. J. W. Steed, H. Zhang and J. L. Atwood, Supramol. Chem., 1996, 7, 37 CrossRef CAS.
  7. A. Collet, Tetrahedron, 1987, 43, 5725 CrossRef CAS.
  8. A. Collet, in Comprehensive Supromolecular Chemistry, ed. D. D. MacNicol, F. Toda and R. Bishop, Pergamon, Oxford, 1996, vol. 6, pp. 281–303 Search PubMed.
  9. J. A. Wytko, C. Boudon, J. Weiss and M. Gross, Inorg. Chem., 1996, 35, 4469 CrossRef CAS.
  10. A. S. Lindsey, J. Chem. Soc., 1965, 1685 RSC.
  11. J. M. Clemente, C. Y. Wong, P. A. Bhattacharya, M. Z. Slawin, D. J. Williams and J. D. Woollins, Polyhedron, 1994, 13, 261 CrossRef CAS; G. A. Fox, S. Bhattacharya and C. G. Pierpont, Inorg. Chem., 1991, 30, 2895 CrossRef CAS.
  12. A. Renault, D. Talham, J. Canceill, P. Batail, A. Collet and J. Lajzerowicz, Angew. Chem., Int. Ed. Engl., 1989, 28, 1249 CrossRef.
  13. D. S. Bohle and D. Stasko, unpublished work.
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