View PDF Version
 
DOI: 10.1039/A707398D (Paper) Reference Section for: Chem. Commun., 1998, 597-598

The first stable copper(II) complex containing four sulfide ligands: synthesis and structural characterization of [Pt2(dppe)2(µ-S)2] and [Cu{Pt2(dppe)2(µ3-S)2}2]2+

(Note: The full text of this document is currently only available in the PDF Version )

Mercè Capdevila, Yolanda Carrasco, Pilar González-Duarte, Agustí Lledós, Joan Sola, Gregori Ujaque, Mercè Capdevila, William Clegg, Robert A. Coxall and Pilar González-Duarte

Abstract

The synthesis and crystal structure of the novel heteropolymetallic aggregate [{Pt2(dppe)2(µ3-S)2}2Cu]- [PF6]2 2 and of its precursor [Pt2(dppe)2(µ-S)2] 1 are reported; 2 has been further characterized by EPR and electronic spectroscopies and the hinged Pt2S2 rings in 1 and 2 have been rationalized by ab initio MP2 calculations.

References

  1. (a) H. Liu, A. L. Tan, Y. Xu, K. F. Mok and T. S. A. Hor, Polyhedron, 1997, 16, 377 CrossRef CAS and references therein; (b) V. W. W. Yam, P. K. Y. Yeung and K. K. Cheung, Angew. Chem., Int. Ed. Engl., 1996, 35, 739 CrossRef CAS.
  2. C. E. Briant, C. J. Gardner, T. S. A. Hor, N. D. Howells and D. M. P. Mingos, J. Chem. Soc., Dalton Trans., 1984, 2645 RSC.
  3. V. W. W. Yam, P. K. Y. Yeung and K. K. Cheung, J. Chem. Soc., Chem. Commun., 1995, 267 RSC.
  4. M. Capdevila, W. Clegg, P. González-Duarte, A. Jarid and A. Lledós, Inorg. Chem., 1996, 35, 490 CrossRef CAS.
  5. E. John, P. K. Bharadwaj, K. Krogh-Jespersen, J. A. Potenza and H. J. Schugar, J. Am. Chem. Soc., 1986, 108, 5015 CrossRef CAS.
  6. K. Fujisawa, Y. Moro-oka and N. Kitajima, J. Chem. Soc., Chem. Commun., 1994, 623 RSC.
  7. R. Ugo, G. La Monica, S. Cenini, A. Segre and F. Conti, J. Chem. Soc. A, 1971, 522 RSC.
  8. M. J. Frisch, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. A. Keith, G. A. Petersson, J. A. Montgomery, K. Raghavachari, M. A. Al-Laham, V. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B. Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andrés, E. S. Replogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Binkley, D. J. De Frees, J. Baker, J. P. Stewart, M. Head-Gordon, C. Gonzalez and J. A. Pople, Gaussian 94; Gaussian Inc., Pittsburg PA, 1995.
  9. C. Möller and M. S. Plesset, Phys. Rev., 1934, 46, 618 CrossRef CAS.
  10. (a) P. J. Hay and W. R. Wadt, J. Chem. Phys., 1985, 82, 299 CrossRef CAS; (b) W. R. Wadt and P. J. Hay, J. Chem. Phys., 1985, 82, 284 CrossRef CAS; (c) A. Höllwarth, M. Böhme, S. Dapprich, A. W. Ehlers, A. Gobbi, V. Jonas, K. F. Köhler, R. Stegmann, A. Veldkamp and G. Frenking, Chem. Phys. Lett., 1993, 208, 237 CrossRef; (d) W. J. Hehre, R. E. Stewart and J. A. Pople, J. Chem. Phys., 1969, 51, 2657 CrossRef CAS.
  11. N. Duran, P. González-Duarte, A. Lledós, T. Parella, J. Sola, G. Ujaque, W. Clegg and K. A. Fraser, Inorg. Chim. Acta, 1997, 265, 89 CrossRef CAS.
  12. B. J. Hathaway and D. E. Billing, Coord. Chem. Rev., 1970, 5, 143 CrossRef CAS.
  13. K. W. Penfield, R. R. Gay, R. S. Himmelwright, N. C. Eickman, V. A. Norris, H. C. Freeman and E. I. Solomon, J. Am. Chem. Soc., 1981, 103, 4382 CrossRef CAS.
  14. U. Sakaguchi and A. W. Addison, J. Chem. Soc., Dalton Trans., 1979, 600 RSC.
  15. L. P. Battaglia, A. Bonamartini Corradi, G. Marcotrigiano, L. Menabue and G. C. Pellacani, Inorg. Chem., 1979, 18, 148 CrossRef.
Click here to see how this site uses Cookies. View our privacy policy here.