Preparation and structure of cis-[Pt(BF2)2(PPh3)2]: the first crystallographically characterised complex containing the BF2 ligand

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Aidan Kerr, Nicholas C. Norman, A. Guy Orpen, Michael J. Quayle, Craig R. Rice, Peter L. Timms, George R. Whittell, Aidan Kerr and Todd B. Marder


Abstract

The platinum compound [Pt(PPh3)2(η-C2H4)] reacts with B2F4 affording the BF2 complex cis-[Pt(BF2)2(PPh3)2] which is characterised by multinuclear NMR studies and X-ray crystallography.


References

  1. M. J. G. Lesley, T. B. Marder, N. C. Norman, C. R. Rice, E. G. Robins, W. R. Roper and G. R. Whittell, manuscript in preparation.
  2. T. Ishiyama, N. Matsuda, N. Miyaura and A. Suzuki, J. Am. Chem. Soc., 1993, 115, 11 018 CrossRef CAS; F. Ozaura, A. Suzuki and N. Miyaura, Organometallics, 1996, 15, 713 CrossRef.
  3. C. N. Iverson and M. R. Smith, J. Am. Chem. Soc., 1995, 117, 4403 CrossRef CAS; C. N. Iverson and M. R. Smith, Organometallics, 1996, 15, 5155 CrossRef CAS.
  4. M. J. G. Lesley, P. Nguyen, N. J. Taylor, T. B. Marder, A. J. Scott, W. Clegg and N. C. Norman, Organometallics, 1996, 15, 5137 CrossRef.
  5. W. Clegg, F. J. Lawlor, G. Lesley, T. B. Marder, N. C. Norman, A. G. Orpen, M. J. Quayle, C. R. Rice, A. J. Scott and F. E. S. Souza, J. Organomet. Chem., in press Search PubMed.
  6. T. R. F. Johann, T. B. Marder, A. G. Orpen, T. M. Peakman, A. J. Scott, W. Clegg, N. C. Norman, M. J. Quayle and C. R. Rice, manuscript in preparation.
  7. M. Camalli, F. Caruso, S. Chaloupka, E. M. Leber, H. Rimml and L. M. Venanzi, Helv. Chim. Acta, 1990, 73, 2263 CrossRef CAS.
  8. P. L. Timms, J. Am. Chem. Soc., 1967, 89, 1629 CrossRef CAS.
  9. H. Nöth, IMEBORON Conference Abstracts, Heidelberg, 1996.
  10. S. Sakaki and T. Kikuno, Inorg. Chem., 1997, 36, 226 CrossRef CAS; Q. Cui, D. G. Musaev and K. Morokuma, Organometallics, 1997, 16, 1355 CrossRef CAS.
  11. L. Trefonas and W. N. Lipscomb, J. Chem. Phys., 1958, 28, 54 CrossRef CAS.
  12. D. R. Russell and P. A. Tucker, J. Chem. Soc., Dalton Trans., 1975, 1752 RSC.
  13. C. N. Wilker, R. Hoffmann and O. Eisenstein, Nouv. J. Chim., 1983, 7, 535 Search PubMed.
  14. G. Schmid and H. Nöth, J. Organomet. Chem., 1967, 7, 129 CrossRef CAS; G. Schmid, W. Petz, W. Arloth and H. Nöth, Angew. Chem., Int. Ed. Engl., 1967, 6, 696 CrossRef.
  15. N. Lu, N. C. Norman, A. G. Orpen, M. J. Quayle, P. L. Timms and G. R. Whittell, unpublished work.
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