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DOI: 10.1039/A707274K (Paper) Reference Section for: Chem. Commun., 1998, 281-282

Resolution and circular dichroism of an asymmetrically cage-opened [60]fullerene derivative

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Jan C. Hummelen , Majid Keshavarz-K , Joost L. J. van Dongen , René A. J. Janssen , E. W. Meijer and Fred Wudl

Abstract

The enantiomers of the first cagewise inherently asymmetric C 60 derivative, i.e. N-MEM (MEM = 2-methoxyethoxymethyl) keto lactam 1, have been separated by HPLC and their chiroptical properties compared with data obtained from C 60 derivatives that are dissymmetric or asymmetric due to chiral addends.

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