Structure and molecular magnetism of the rutile-related compounds M(dca)2, M = CoII, NiII, CuII, dca = dicyanamide, N(CN)2

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Stuart R. Batten, Richard Robson, Stuart R. Batten, Paul Jensen, Boujemaa Moubaraki and Keith S. Murray


Abstract

The isomorphous rutile-related network structures of Co(dca)2, Ni(dca)2 and Cu(dca)2, dca = dicyanamide, N(CN)2, are shown to behave as ferromagnets (Tc = 9 and 20 K) and a near-paramagnet, respectively.


References

  1. R. Robson, B. F. Abrahams, S. R. Batten, R. W. Gable, B. F. Hoskins and J. Liu, Supramolecular Architecture, ed. T. Bein, ACS Symp. Ser. 499, Washington, DC, 1992, ch. 19 Search PubMed.
  2. B. F. Abrahams, S. R. Batten, H. Hamit, B. F. Hoskins and R. Robson, Angew. Chem., Int. Ed. Engl., 1996, 35, 1691 CrossRef; B. F. Hoskins, R. Robson and D. A. Slizys, J. Am. Chem. Soc., 1997, 119, 2952 CrossRef CAS; B. F. Abrahams, S. J. Egan, B. F. Hoskins and R. Robson, Chem. Commun., 1996, 1099 RSC.
  3. C. L. Bowes and G. A. Ozin, Adv. Mater., 1996, 8, 13 CAS; M. J. Zaworotko, Coord. Chem. Rev., 1994, 283 CAS; M. Bertelli, L. Carlucci, G. Ciani, D. M. Proserpio and A. Sironi, J. Mater. Chem., 1997, 7, 1271 RSC; K. A. Hirsch, S. R. Wilson and J. S. Moore, Inorg. Chem., 1997, 36, 2960 CrossRef CAS; O. M. Yaghi, C. E. Davis, G. Li and H. Li, J. Am. Chem. Soc., 1997, 119, 2861 CrossRef CAS.
  4. H. O. Stumpf, L. Ouahab, Y. Pei, D. Grandjean and O. Kahn, Science, 1993, 261, 447 CrossRef; H. O. Stumpf, L. Ouahab, Y. Pei, P. Bergerat and O. Kahn, J. Am. Chem. Soc., 1994, 116, 3866 CrossRef.
  5. P. Day, J. Chem. Soc., Dalton Trans., 1997, 701 RSC; H. Tamaki, Z. J. Zhong, N. Matsumoto, S. Kida, M. Koikawa, N. Achiwa, Y. Hashimoto and H. Okawa, J. Am. Chem. Soc., 1992, 114, 6974 CrossRef; S. Decurtins, H. W. Schmalle, H. R. Oswald, A. Linden, J. Ensling, P. Gutlich and A. Hauser, Inorg. Chim. Acta, 1994, 216, 65 CrossRef CAS; L. O. Atovmyan, G. V. Shilov, N. S. Ovanesyan, A. A. Pyalling, R. N. Lyubovskaya, E. I. Zhilyaeva and Y. G. Morozov, Synth. Met., 1995, 71, 1809 CrossRef CAS.
  6. S. R. Batten, B. F. Hoskins and R. Robson, J. Chem. Soc., Chem. Commun., 1991, 445 RSC; S. R. Batten, B. F. Hoskins and R. Robson, unpublished work.
  7. S. R. Batten, B. Moubaraki, K. S. Murray and R. Robson, unpublished work.
  8. H. Köhler, Z. Anorg. Allg. Chem., 1964, 331, 237 CrossRef.
  9. M. Hvastijova, J. Kozisek, J. Kohout, L. Jäger and H. Fuess, Transition Met. Chem., 1995, 20, 276 CAS; M. Hvastijova, J. Kohout, J. Mrozinski and L. Jäger, Pol. J. Chem., 1995, 69, 852 CAS.
  10. O. Kahn, Molecular Magnetism, VCH, New York, 1994, ch. 12, p. 287 Search PubMed; Adv. Inorg. Chem., 1995, 43, 179 Search PubMed.
  11. P. Day, Chem. Soc. Rev., 1993, 51 RSC and references therein.
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