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DOI: 10.1039/A707228G (Paper) Reference Section for: Chem. Commun., 1998, 45-46

Supramolecular self-assembly of a toroidal inclusion complex, [NH4][Co8(MeCO2)8(OMe)16][PF6]

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James K. Beattie, Trevor W. Hambley, John A. Klepetko and Peter Turner

Abstract

Diamagnetic [NH4][Co8(MeCO2)8(OMe)16][PF6], a compound with eight cobalt atoms bridged by methoxy and acetato ligands so as to form a planar ring with an ammonium ion at its centre, is isolated from the reaction between cobalt(III) acetate and methanol in the presence of NH4PF6.

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