The facile loss of formic acid from an anion system in which the charged and reacting centres cannot interact

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Suresh Dua, John H. Bowie, Suresh Dua, Blas A. Cerda and Chrys Wesdemiotis


Abstract

Both the 3-[2-(2-formyloxy-1,3-[2H6]propyl)]adamantane carboxyate anion and cation undergo loss of HCO2D from the 3 substituent by processes which occur remote from and uninfluenced by the carboxylate charged centre.


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