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DOI: 10.1039/A705522F (Paper) Reference Section for: Chem. Commun., 1998, 141-142

Formation of an unusual tetralithium diplatinum complex [Pt(C[triple bond, length half m-dash]CBut)2(PPh2O)2Li2(µ-H2O)(Me2CO)2]2 containing µ3-PPh2O– Ligands

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Larry R. Falvello, Juan Forniés, Antonio Martín, Larry R. Falvello, Elena Lalinde, Teresa Moreno and Jorge Sacristán

Abstract

The very unusual complex [Pt(C[triple bond, length half m-dash]CBut)2(PPh2O)2Li2(µ-H2O)(Me2CO)2]2 2 is obtained by the reaction of ‘Li2[Pt(C[triple bond, length half m-dash]CBut)4]’ with an excess of PPh2H in acetone–ethanol and possesses an unusual linear chain of four Li atoms sandwiched between two square planar dianionic units trans-–OPPh2{Pt(C[triple bond, length half m-dash]CBut)2}PPh2O–, to which it is bound through µ3-PPh2O– bridging ligands.

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