⁷¹Ga and ³¹P solid state NMR: a powerful tool for the characterization of the first gallium phosphonates

Abstract

Two new gallium phosphonates Ga(OH)(O₃PC₂H₄- CO₂H)·H₂O 1 and Ga₃(OH)₃(O₃PC₂H₄CO₂)₂·2H₂O 2 are prepared and characterized, using ³¹P MAS and ⁷¹Ga static NMR spectroscopy, showing a good correspondence between the fitted NMR parameters and the crystallographic data.

References

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