Fourier transform infrared spectrometry: a versatile technique for real world samples†

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Llewellyn Rintoul, Helen Panayiotou, Serge Kokot, Graeme George, Gregory Cash, Ray Frost, Thuy Bui and Peter Fredericks


Abstract

The versatility of FTIR spectrometry was explored by considering a variety of samples drawn from industrial applications, materials science and biomedical research. These samples included polymeric insulators, bauxite ore, clay, human hair and human skin. A range of sampling techniques suitable for these samples is discussed, in particular FTIR microscopy, FTIR emission spectroscopy, attenuated total reflectance and photoacoustic FTIR spectrometry. The power of modern data processing techniques, particularly multivariate analysis, to extract useful information from spectral data is also illustrated.


References

  1. P. R. Griffiths and J. de Haseth, Fourier Transform Infrared Spectrometry, Wiley, New York, 1986 Search PubMed.
  2. B. C. Smith, Fundamentals of Fourier Transform Infrared Spectroscopy, CRC Press, Boca Raton, FL, 1996 Search PubMed.
  3. K. Nishikida, E. Nishio and W. Hannah, Selected Applications of Modern FT-IR Techniques, Gordon and Breach, New York, 1996 Search PubMed.
  4. S. Johnston, Fourier Transform Infrared: a Constantly Evolving Technology, Ellis Horwood, Chichester, 1991 Search PubMed.
  5. Practical Fourier Transform Infrared Spectroscopy: Industrial and Laboratory Chemical Analysis, eds. Ferraro, J. R., and Krishnan, K., Academic Press, New York, 1990 Search PubMed.
  6. A. M. Vassallo, P. A. Cole-Clarke, L. S. K. Pang and A. J. Palmisana, Appl. Spectrosc., 1992, 46, 73 CAS.
  7. R. G. Messerschmidt and M. A. Harthcock, Infrared Microspectroscopy. Theory and Applications, Marcel Dekker, New York, 1988 Search PubMed.
  8. E. N. Lewis, L. H. Kidder, I. W. Levin, V. D. Kleiman and E. J. Hellwell, Opt. Lett., 1997, 22, 742.
  9. C. Marcott, G. M. Story, A. E. Dowrey, R. C. Reeder and I. Noda, Mikrochim. Acta (Suppl.), 1996, 14, 157 Search PubMed.
  10. V. C. Farmer, The Infrared Spectra of Minerals, Mineralogical Society, London, 1974 Search PubMed.
  11. K. Jonas and K. Solymar, Acta Chim. Acad. Sci. Hung., 1970, 66, 1 CAS.
  12. L. Rintoul and P. M. Fredericks, Appl. Spectrosc., 1995, 49, 1608.
  13. E. Wentrup-Byrne, L. Rintoul, J. L. Smith and P. M. Fredericks, Appl. Spectrosc., 1995, 49, 1028 CAS.
  14. D. L. Massart, M. G. M. Vandeginste, S. N. Deming, Y. Michotte and L. Kaufman, Chemometrics: A Textbook, Elsevier, Amsterdam, 1988 Search PubMed.
  15. M. Otto, Chemom. Intell. Lab. Syst., 1988, 4, 101 CrossRef.
  16. R. R. Meglen, Chemom. Intell. Lab. Syst., 1988, 3, 17 CrossRef CAS.
  17. J. K. Wilmhurst, J. Chem. Phys., 1963, 39, 2545 CrossRef.
  18. T. R. Kozlowski, Appl. Opt., 1968, 7, 795 CAS.
  19. G. A. George, M. Celina, A. M. Vassallo and P. A. Cole-Clark, Polym. Degrad. Stab., 1995, 48, 199 CrossRef CAS.
  20. R. L. Frost and A. M. Vassallo, Clays Clay Miner., 1996, 44, 635 CAS.
  21. N. J. Harrick, Internal Reflection Spectroscopy, Wiley-Interscience, New York, 1967 Search PubMed.
  22. N. A. Puttnam, J. Soc. Cosmet. Chem., 1972, 23, 209 Search PubMed.
  23. R. E. Baier, J. Soc. Cosmet. Chem., 1978, 29, 283 Search PubMed.
  24. D. A. C. Compton, S. L. Hill, N. A. Wright, M. A. Druy, J. Piche, W. A. Stevenson and D. W. Vidrine, Appl. Spectrosc., 1988, 42, 972 CAS.
  25. J. A. Graham, W. M. Grim and W. G. Fateley, in Fourier Transform Infrared Spectroscopy, ed. Ferraro, J. R., and Basile, L. J., Academic Press, New York, 1985, vol. 4, pp. 345–392 Search PubMed.
  26. D. W. Vidrine, in Fourier Transform Infrared Spectroscopy, ed., Ferraro, J. R., and Basile, L. J.Academic Press, New York, 1982, vol. 3, pp. 125–148 Search PubMed.
  27. C. Q. Yang, R. R. Bresee and W. G. Fateley, Appl. Spectrosc., 1987, 41, 889 CAS.
  28. E. A. Carter, P. M. Fredericks and J. S. Church, Text. Res. J., 1996, 66, 787 Search PubMed.
  29. R. M. Dittmar, J. L. Chao and R. A. Palmer, Appl. Spectrosc., 1991, 45, 1104 CAS.
  30. M. G. Sowa and H. H. Mantsch, Appl. Spectrosc., 1994, 48, 316 CAS.
  31. L. Bertrand, Appl. Spectrosc., 1988, 42, 134 CAS.
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