DOI: 10.1039/A703439C
(Paper)
Reference Section for: J. Chem. Soc., Perkin Trans. 2, 1997, 1621-1624
Formation of silylketenes via a 1,3-silyl shift. A theoretical study
(Note: The full text of this document is currently only available in the PDF Version )
Magali Oblin, Frédéric Fotiadu, Michel Rajzmann and Jean-Marc Pons
Abstract
Ab initio and semiempirical calculations show that the formation of silylketenes from silyloxyacetylenes by a 1,3-silyl shift should occur through a concerted closed-shell mechanism involving retention (rather than inversion) of configuration at the silicon centre.
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