Silacyclopentadienylidene, the first silylene incorporated in a silole ring

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Masahiro Kako, Shota Oba, Ryuji Uesugi, Shunetsu Sumiishi, Yasuhiro Nakadaira, Kiyoshi Tanaka and Toshikazu Takada


Abstract

Silacyclopentadienylidene 1 was generated photochemically using 7-silanorbornadiene and norbornene precursors and observed in frozen hydrocarbon matrices at 77 K.


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