DOI: 10.1039/A607105H
(Paper)
Reference Section for: J. Chem. Soc., Perkin Trans. 2, 1997, 667-668
FTIR spectra of matrix isolated 2-methylbenzonorbornen-2-yl-type cations
(Note: The full text of this document is currently only available in the PDF Version )
Hrvoj Vančik, Alexander M. Genaev and Vyacheslav G. Shubin
Abstract
FTIR spectra suggest that ionization of
2-exo-chloro-2-methylbenzonorbornene![[hair space]](https://www.rsc.org/images/entities/b_char_200a.gif)
in an SbF5 matrix at -196 °C leads to
2-methyl-2-benzonortricyclyl cation which rearranges into a partially
π-bridged 2-methylbenzonorbornen-2-yl ion at
-123 °C.
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