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DOI: 10.1039/A605421H (Paper) Reference Section for: J. Chem. Soc., Perkin Trans. 2, 1997, 243-248

Solute–solvent and solvent–solvent interactions in binary solvent mixtures. Part 5. Preferential solvation of solvatochromic indicators in mixtures of propan-2-ol with hexane, benzene, ethanol and methanol

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Clara Ràfols, Martí Rosés and Elisabeth Bosch

Abstract

The solvatochromic shifts of several indicators {2,6-diphenyl-4-(2,4,6-triphenyl-1-pyridinio)-1-phenolate [Reichardt’s ET(30) betaine dye], 4-nitroanisole, 4-nitroaniline and N,N-diethyl-4-nitroaniline} have been measured in binary mixtures of propan-2-ol with hexane, benzene, ethanol and methanol at 25 °C over the whole range of solvent composition. From the UV–VIS spectroscopic data the preferential solvation of the indicators has been studied. The solvatochromic parameters ET(30), π*, α and β of the binary solvent mixtures studied have been calculated from the solvatochromic shifts.

References

  1. C. Reichardt, Solvents and Solvent Effects in Organic Chemistry, VCH, Weinheim, 2nd edn, 1988 Search PubMed.
  2. M. J. Kamlet and R. W. Taft, J. Am. Chem. Soc., 1976, 98, 377 CrossRef CAS.
  3. M. J. Kamlet and R. W. Taft, J. Am. Chem. Soc., 1976, 98, 2886 CrossRef CAS.
  4. M. J. Kamlet, J.-L. M. Abboud and R. W. Taft, J. Am. Chem. Soc., 1977, 99, 6027 CrossRef CAS.
  5. M. J. Kamlet, J.-L. M. Abboud, M. H. Abraham and R. W. Taft, J. Org. Chem., 1983, 48, 2877 CrossRef CAS.
  6. E. Bosch, F. Rived and M. Rosés, J. Chem. Soc., Perkin Trans. 2, 1996, 2177 RSC.
  7. C. Reichardt, Chem. Rev., 1994, 94, 2319 CrossRef CAS.
  8. E. Bosch and M. Rosés, J. Chem. Soc., Faraday Trans., 1992, 88, 3541 RSC.
  9. M. Rosés, C. Ràfols, J. Ortega and E. Bosch, J. Chem. Soc., Perkin Trans. 2, 1995, 1607 RSC.
  10. J. Ortega, C. Ràfols, E. Bosch and M. Rosés, J. Chem. Soc., Perkin Trans. 2, 1996, 1497 RSC.
  11. E. Bosch, M. Rosés, K. Herodes, I. Koppel, I. Leito, I. Koppel and V. Taal, J. Phys. Org. Chem., 1996, 9, 403 CrossRef CAS.
  12. R. D. Skwierczynski and K. A. Connors, J. Chem. Soc., Perkin Trans. 2, 1994, 467 RSC.
  13. J. L. Beltran, G. Centeno, A. Izquierdo and M. D. Prat, Talanta, 1992, 39, 981 CrossRef CAS.
  14. Y. Marcus, J. Solution Chem., 1991, 20, 929 CAS.
  15. Y. Marcus and Y. Migron, J. Phys. Chem., 1991, 95, 400 CrossRef CAS.
  16. E. Bosch, F. Rived and M. Rosés, J. Phys. Org. Chem., 1994, 7, 696 CrossRef CAS.
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