DOI: 10.1039/A605298C
(Paper)
Reference Section for: J. Chem. Soc., Perkin Trans. 2, 1997, 585-588
Kinetics of desolvation from crystalline inclusion compounds of a diol host with methanol and ethanol
(Note: The full text of this document is currently only available in the PDF Version )
Susan A. Bourne, Bruce M. Oom and Fumio Toda
Abstract
The crystal structures of the inclusion compounds of (4R,5R)-4,5-bis(hydroxydiphenylmethyl)-2,2-dimethyl-1 ,3-dioxolane with methanol and ethanol have been elucidated. Their isothermal kinetics of desolvation have been studied. Both lose the guest in a single deceleratory step, and a kinetic model based on a diffusion mechanism was found to be the best description for this process.
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