DOI: 10.1039/A706238I
(Paper)
Reference Section for: J. Chem. Soc., Perkin Trans. 1, 1997, 3297-3298
Stereoselective epoxidation of electron poor dienes using poly(L-leucine)
(Note: The full text of this document is currently only available in the PDF Version )
Joanne V. Allen, Michael W. Cappi, Pierre D. Kary, Stanley M. Roberts, Natalie M. Williamson and L. Eduardo Wu
Abstract
Poly(L-leucine) catalysed oxidation of dienes 2, 3, 10, 16 and 18 and the triene 17 furnishes the corresponding epoxides 4, 5, 11, 19, 21 and 20 respectively in good to excellent yield and in states of high optical purity. Some regioselective reactions of the saturated epoxy ketones 5 and 11 are described.
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