Synthesis and palladium-catalysed transformation of an annelated barrelene

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Gerald Dyker, Thomas Kerl, Peter G. Jones, Ina Dix and Peter Bubenitschek


Abstract

The annelated barrelene 8 is easily accessible in a three-step reaction procedure from simple starting materials. An intermolecular palladium-catalysed arylation at the strained tetrasubstituted double bond of the barrelene finally leads to polycyclic hydrocarbons.


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