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DOI: 10.1039/A604103E (Paper) Reference Section for: J. Chem. Soc., Perkin Trans. 1, 1997, 295-302

New large cage receptors. An example of selective phloroglucinol binding

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Ian M. Atkinson, Anthony R. Carroll, Ronald J. A. Janssen, Leonard F. Lindoy, Owen A. Matthews and George V. Meehan

Abstract

An efficient and convergent procedure has been developed for the synthesis of a range of related, large-ring monocyclic and bicyclic (cage) receptor molecules. The interaction of one such cage 8b, incorporating three central pyridyl groups, with a number of mono-, di- and tri-phenol derivatives has been investigated. In accordance with the inference from molecular modelling, this cage exhibits preferential inclusive binding of the symmetrical guest phloroglucinol.

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