Issue 3, 1997

Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge-H insertion process

Abstract

Gas-phase rate constants, obtained from 292-557 K, yield an activation energy of -10.6±1.1kJmol-1 for the insertion reaction of GeH2 into a Ge-H bond (of triethylgermane); these results indicate the likely involvement of an intermediate complex.

Article information

Article type
Paper

Mendeleev Commun., 1997,7, 87-88

Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge-H insertion process

R. Becerra, S. E. Boganov, M. P. Egorov, O. M. Nefedov and R. Walsh, Mendeleev Commun., 1997, 7, 87 DOI: 10.1070/MC1997v007n03ABEH000787

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