Issue 6, 1997
From the journal:

Mendeleev Communications

A new, general route to 1-cloro-1-ethynylcyclopropanes via chloro(trimethylsilylethynyl)carbene

Konstantin N. Shavrin,   Irina V. Krylova,   Inna B. Shvedova  and  Oleg M. Nefedov  

Abstract

A new, general route to 1-chloro-1-ethynylcyclopropanes 6 has been developed via cycloaddition of previously unknown chloro(trimethylsilylethynyl)carbene 4b to olefins with formation of the corresponding cyclopropanes 5a-f in 35-65% yield and subsequent removal of the trimethylsilyl group under the action of KF2H 2 O in aqueous DMF to give cyclopropanes 6 in up to 80% yield.

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Article information

DOI
https://doi.org/10.1070/MC1997v007n06ABEH000759
Article type
Paper

Mendeleev Commun., 1997,7, 218-219

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A new, general route to 1-cloro-1-ethynylcyclopropanes via chloro(trimethylsilylethynyl)carbene

K. N. Shavrin, I. V. Krylova, I. B. Shvedova and O. M. Nefedov, Mendeleev Commun., 1997, 7, 218 DOI: 10.1070/MC1997v007n06ABEH000759

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