The decomposition curve of methane hydrate under pressure shows a break at 6.2 kbar, indicating the formation of a second hydrate; at 5 to 6 kbar the decomposition temperature of the first hydrate reaches a maximum at 47.7°C and the decomposition temperature of the denser hydrate increases to 57.3°C at 15 kbar.
Y. A. Dyadin, E. Y. Aladko and E. G. Larionov, Mendeleev Commun., 1997, 7, 34 DOI: 10.1070/MC1997v007n01ABEH000655
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