View PDF Version
 
DOI: 10.1039/A702862H (Paper) Reference Section for: J. Mater. Chem., 1997, 7, 2269-2272

Effect of microstructure on the stability of nanocrystalline tin dioxide ceramics

(Note: The full text of this document is currently only available in the PDF Version )

Svetlana M. Kudryavtseva, Alexei A. Vertegel, Sergei V. Kalinin, Nikolai N. Oleynikov, Ludmila I. Ryabova, Leonid L. Meshkov, Sergei N. Nesterenko, Marina N. Rumyantseva and Alexander M. Gaskov

Abstract

Powdered nanocrystalline tin dioxide has been prepared by two different methods: conventional hydrolysis of SnCl4 solution and the so-called criosol technique. The latter involves treatment of a sodium stannate solution by a cation exchange resin in the H+ form and subsequent freeze drying. The microstructure, composition, specific surface area and electrical properties of the samples were investigated. The application of the criosol technique was shown to result in stable nanoscale particles of tin dioxide. The sintered pellets obtained by this method are characterised by significantly higher values of the resistance in comparison to material prepared by the conventional technique.

References

  1. W. Gopel and K. D. Schierbaum, Sens. Actuators B, 1995, 26–27, 1 CrossRef.
  2. C. Xu, J. Tamaki, N. Miura and N. Yamazoe, Sens. Actuators B, 1991, 3, 147 CrossRef.
  3. C. Xu, J. Tamaki, N. Miura and N. Yamazoe, Electrochem. Soc. Jpn., 1990, 58, 1143 Search PubMed.
  4. C. Xu, J. Tamaki, N. Miura and N. Yamazoe, J. Mater. Sci., 1992, 27, 963 CAS.
  5. G. Behr and W. Fliegel, Sens. Actuators B, 1995, 26–27, 33 CrossRef.
  6. M. J. Hampden-Smith, T. A. Wark and C. J. Brinker, Coord. Chem. Rev., 1992, 112, 81 CrossRef CAS.
  7. G. Pfaff, Sens. Actuators B, 1994, 20, 43 CrossRef CAS.
  8. R. Botter, T. Aste and D. Beruto, Sens. Actuators B, 1994, 22, 27 CrossRef.
  9. A. Diegues, A. Romano-Rodrigues, J. R. Morante, U. Weimar, M. Schweizer-Berberich and W. Gopel, Sens. Actuators B, 1996, 31, 1 CrossRef.
  10. M. Ando, T. Tsuchida, N. Miura and N. Yamazoe, J. Chem. Soc. Jpn., 1996, 4, 348 Search PubMed.
  11. A. A. Vertegel, S. V. Kalinin, N. N. Oleynikov and Yu. D. Tretyakov, J. Non-Cryst. Solids, 1995, 181, 146 CrossRef CAS.
  12. A. A. Vertegel, S. V. Kalinin, N. N. Oleynikov and Yu. D. Tretyakov, Chem. Phys. Lett., 1996, 262, 455 CrossRef CAS.
  13. A. A. Vertegel, Dissertation for Candidate of Chemical Sciences Degree, Moscow State University, 1996(in Russian).
  14. I. M. Lifshits and V. V. Slezov, Zh. Exp. Teor. fiz. (J. Exp. Theor. Phys.), 1958, 35, 479 Search PubMed (in Russian).
  15. I. M. Lifshits and V. V. Slezov, Fiz. tverdogo Tela (Phys. Solid state), 1959, 1, 1401 Search PubMed (in Russian).
  16. C. J. Fonstad and R. H. Rediker, J. Appl. Phys., 1971, 42, 2911 CrossRef.
  17. J. Tamaki, T. Maekawa, N. Miura and N. Yamazoe, Sens. Actuators B, 1992, 9, 197 CrossRef.
  18. M. N. Rumyantseva, M. Labeau, J. P. Senateur, G. Delabouglise, M. N. Boulova and A. M. Gaskov, J. Mater. Sci. Eng. B, 1996, 41, 228 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.