New preparation method of Lan+1NinO3n+1–δ (n=2, 3)

(Note: The full text of this document is currently only available in the PDF Version )

Maria Deus Carvalho, Fernanda Madalena A. Costa, Isabel da Silva Pereira, Alain Wattiaux, Jean Marc Bassat, Jean Claude Grenier and Michel Pouchard


Abstract

Samples Lan+1NinO3n+1–δ(n=2,3) have been prepared by two different methods, which lead to different oxygen stoichiometry values. Materials obtained by the citrate route always show higher content of Ni3+ , which can be rationalized by the high reactivity and the original morphology of the precursors obtained by this method.


References

  1. P. Lacorre, J. Solid State Chem., 1992, 97, 495 CrossRef CAS.
  2. P. Lacorre, Actual. Chim., 1995, 3, 16 Search PubMed.
  3. R. A. Mohan-Ram, L. Ganapathi, P. Ganguly and C. R. N. Rao, Solid State Commun., 1986, 63, 139.
  4. K. Sreedhar, M. Mc Elfresh, D. Perry, D. Kim, P. Metcalf and M. Honig, J. Solid State Chem., 1994, 110, 208 CrossRef CAS.
  5. J. Drennan, C. P. Tavares and B. C. H. Steele, Mater. Res. Bull., 1982, 17, 621 CrossRef CAS.
  6. Z. Zhang, M. Greenblatt and J. B. Goodenough, J. Solid State Chem., 1994, 108, 402 CrossRef CAS.
  7. Z. Zhang and M. Greenblatt, J. Solid State Chem., 1994, 111, 141 CrossRef CAS.
  8. Z. Zhang and M. Greenblatt, J. Solid State Chem., 1995, 117, 236 CrossRef CAS.
  9. P. Dordor, E. Marquestaut and G. Villeneuve, Rev. Phys. Appl., 1985, 20, 795 Search PubMed.
  10. P. Barboux, P. Griesmar, F. Ribot and L. Mazerolles, J. Solid State Chem., 1995, 117, 343 CrossRef CAS.
  11. S. Taniguchi, T. Nishikawa, Y. Yasui, Y. Kobayashi, J. Takeda, S. I. Shamoto and M. Sato, Phys. Soc. Jpn., 1995, 64, 1644 Search PubMed.
  12. C. Brisi, M. Vallino and F. Abbattista, J. Less Common Met., 1981, 79, 215 Search PubMed.
  13. K. Tkalich, V. P. Glazkov, V. A. Somenkov, S. Shil'Shteoin, A. E. Kar'Kin and A. V. Mirmel'Shtein, Superconductivity, 1991, 4, 2280 Search PubMed.
  14. A. Demourgues, F. Weill, J. C. Grenier, A. Wattiaux and M. Pouchard, Physica C, 1992, 192, 425 CrossRef CAS.
  15. A. Demourgues, F. Weill, B. Darriet, A. Wattiaux, J. C. Grenier, P. Gravereau and M. Pouchard, J. Solid State Chem., 1993, 106, 317 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.