DOI: 10.1039/A704788F
(Paper)
Reference Section for: J. Chem. Res. (S), 1997, 418-419
Synthesis of Cathasterone and its Related Putative Intermediates in Brassinolide Biosynthesis†
(Note: The full text of this document is currently only available in the PDF Version )
Suguru Takatsuto, Hiroki Kuriyama, Takahiro Noguchi, Hiroyuki Suganuma, Shozo Fujioka and Akira Sakurai
Abstract
The putative intermediates in brassinolide biosynthesis, 22α-hydroxycampesterol 1, 6-deoxocathasterone and its 6α-hydroxylated compound 3, as well as cathasterone 4, are synthesized from a known (22E,24S)-6β-methoxy-3α,5-cyclo-5α-ergost-22-ene 5.
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