DOI: 10.1039/A704509C
(Paper)
Reference Section for: J. Chem. Res. (S), 1997, 430-431
Environmentally Friendly Catalysis using Supported Reagents: Enhanced Selectivity without Loss in Activity in the Alkylation of Benzene using Hexagonal Mesoporous Silica (HMS)-supported Aluminium Chloride†,1
(Note: The full text of this document is currently only available in the PDF Version )
James H. Clark, Peter M. Price, Keith Martin, Duncan J. Macquarrie and Tony W. Bastock
Abstract
Substantial increases in selectivity towards monoalkylation of benzene with alkenes can be achieved through the use of mesoporous HMS as support for immobilised aluminium chloride and through the use of external site poisons while maintaining activities comparable to homogeneous AlCl3.
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