DOI: 10.1039/A703094K
(Paper)
Reference Section for: J. Chem. Res. (S), 1997, 3-5
Photodecarbonylation of 2,2,6,6-TetrasubstitutedCyclohex-3-enones to Vinylcyclopropanes†
(Note: The full text of this document is currently only available in the PDF Version )
Sven Andresen and Paul Margaretha
Abstract
On irradiation (λ=300 nm),2,2,6,6-tetramethylcyclohex-3-enone (1) is cleanly converted into1-(2,2-dimethylcyclopropyl)-2-methylpropene (3); similarly,6-oxo-1,5,5-trimethylcyclohex-2-ene-1-carbonitrile (2) affords amixture of (Z )- and(E )-3-(2,2-dimethylcyclopropyl)-2-methylpropenonitriles4a and 4b.
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