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DOI: 10.1039/A702966G (Paper) Reference Section for: J. Chem. Res. (S), 1997, 464-465

Kinetics of the solvolysis of the Chloropentakis(methylamine)cobalt(III) Ion in Water–Methanol and Water–Propan-2-ol Mixtures†

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Deng Wenjie, Ye Xiaolan, Wang Huatong and Hu Kecheng

Abstract

The solvolysis kinetics of [Co(NH2Me)5Cl]2+ in water–methanol and water–propan-2-ol mixtures are discussed in terms of solvent effects and the structure of the complex.

References

  1. M. F. Amira, S. A. El-Shazly, S. A. Sallam and M. M. Khalil, Transition Met. Chem., 1987, 12, 25 Search PubMed.
  2. A. S. Babaqi, M. T. Mohamed, S. S. Massoud and M. F. Amira, Transition Met. Chem., 1988, 13, 201 Search PubMed.
  3. A. C. Dash, N. C. Naik and R. K. Nanda, Indian J. Chem., 1988, 27, 394 Search PubMed.
  4. K. H. Halawani and C. F. Wells, J. Chem. Res., 1988, (S) 58; (M) 0501 Search PubMed.
  5. G. A. Lawrance, K. Schneider and R. Van Eldik, Inorg. Chem., 1984, 23, 3922 Search PubMed.
  6. G. Akerlof, J. Am. Chem. Soc., 1932, 54, 4125 Search PubMed.
  7. E. Granwald and S. Winstein, J. Am. Chem. Soc., 1948, 70, 846 Search PubMed.
  8. K. Nakanishi, Bull. Chem. Soc J., 1960, 33, 793 Search PubMed.
  9. E. M. Arentt, W. G. Bentrade, J. J. Bruke and P. J. Duggleby, J. Am. Chem. Soc., 1965, 87, 154 Search PubMed.
  10. C. F. Wells, J. Chem. Soc., Faraday Trans., 1970, 66, 204 Search PubMed; J. Chem. Soc., Faraday Trans. 1, 1974, 70, 694 Search PubMed.
  11. H. S. Frank and M. W. Evans, J. Chem. Phys., 1945, 13, 507 Search PubMed; H. S. Frank and W. Y. Wen, Faraday Discuss. Chem. Soc., 1957, 24, 133 Search PubMed; G. Nemethy and H. A. Sheraga, J. Chem. Phys., 1962, 36, 3383, 3401 Search PubMed; N. Laiden and G. Nemethy, J. Phys. Chem., 1970, 74, 3501 Search PubMed.
  12. C. N. Rlgy and C. F. Wells, J. Chem. Soc., Dalton Trans., 1980, 2405 Search PubMed; 1982, 1617.
  13. G. M. El-Subruiti, C. F. Wells and I. M. Sidahmed, Int. J. Chem. Kinet., 1990, 22, 891 Search PubMed; 1991, 23, 161.
  14. A. C. Dash and N. Dash., Int. J. Chem. Kinet., 1990, 22, 1237 Search PubMed.
  15. K. H. Halawani and C. F. Wells, J. Chem. Soc., Faraday Trans. 1, 1989, 85, 2999 Search PubMed; Int. J. Chem. Kinet., 1995, 27, 89 Search PubMed.
  16. M. M. Elsemongy and M. F. Amira, J. Indian Chem. Soc., 1980, 506 Search PubMed.
  17. C. F. Wells, J. Chem. Soc., Faraday Trans. 1, 1977, 73, 1851 Search PubMed.
  18. C. F. Wells, J. Chem. Soc., Faraday Trans. 1, 1973, 69, 984 Search PubMed.
  19. I. M. Sidahmed and C. F. Wells, J. Chem. Soc., Dalton Trans., 1983, 1035 Search PubMed.
  20. R. Mitzner, P. Blankenberg and W. Depkat, Z. Chem., 1969, 2, 68 Search PubMed.
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