Catalytic Dehydrocoupling of Silane by a Homogenous Rhodium Complex with Water†
(Note: The full text of this document is currently only available in the PDF Version )
Min Shi and Kenneth M. Nicholas
Abstract
Organosilicon hydrides are oxidized to the corresponding silanols in high yield in a homogenous phase in the presence of a small amount of water and a catalytic amount of a rhodium complex.
References
L. H. Sommer and
G. A. Parker, unpublished work cited in
L. H. Sommer,
Stereochemistry, Mechanism and Silicon,
McGraw-Hill,
New York,
1965,
p. 110 Search PubMed.
Y. Nagai, K. Honda and T. Migita, J. Organomet. Chem., 1967, 8, 372 Search PubMed.
G. H. Barnes, Jr. and N. E. Daughenbaugh, J. Org. Chem., 1966, 31, 885 Search PubMed.
Click here to see how this site uses Cookies. View our privacy policy here.