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DOI: 10.1039/A700397H (Paper) Reference Section for: J. Chem. Res. (S), 1997, 270-271

Crystal Structure of(E )-1,2-Bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, the trans -Dimer of3-Methyl-3-nitrosobutan-2-one

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Brian G. Gowenlock and Kevin J. McCullough

Abstract

The solid state structure of(E )-1,2-bis(1,1-dimethyl-2-oxopropyl)diaz-1-ene-1,2-diium-1,2-diolate, (3a), the trans -dimer of3-methyl-3-nitrosobutan-2-one, has been determined by X-raycrystallographic analysis; subsequent comparison of the observedgeometrical parameters for 3a with the literature values foreleven other trans or (E )-dimers suggests thatthere is no correlation between the N—N distances in thesedimers and their respective rates of dissociation to monomer insolution.

References

  1. B. G. Gowenlock, K. J. McCullough and R. B. Manson, J. Chem. Soc., Perkin Trans. 2, 1988, 701 RSC.
  2. B. G. Gowenlock and K. J. McCullough, J. Chem. Soc., Perkin Trans. 2, 1989, 551 RSC.
  3. B. G. Gowenlock and K. J. McCullough, J. Chem. Res., 1993, (S), 360; (M) 2481 Search PubMed.
  4. L. Batt and B. G. Gowenlock, J. Chem. Soc., 1960, 376 RSC.
  5. J. G. Aston, D. F. Menard and M. G. Mayberry, J. Am. Chem. Soc., 1932, 54, 1530 CrossRef CAS.
  6. M. B. Hursthouse, A. I. Karaulov, M. Ciechanowicz-Rutkowska, A. Kolasa and W. Zankowska-Jasinska, Acta Crystallogr., Sect. C, 1992, 48, 1257 CrossRef.
  7. SHELXS-86, G. M. Sheldrick, Acta Crystallogr., Sect A, 1990, 46, 467 Search PubMed.
  8. SHELXTL/PC (ver. 5.03), G. M. Sheldrick, Siemens Analytical X-ray Instruments, Madison, WI, USA.
  9. F. P. Boer and J. W. Turley, J. Am. Chem. Soc., 1969, 91, 1371 CrossRef CAS.
  10. M. Tanimura, K. Kobori, M. Kashiwagi and Y. Kinoshita, Bull. Chem. Soc. Jpn., 1970, 43, 1962 CAS.
  11. D. A. Dieterich, I. C. Paul and K. Y. Curtis, J. Am. Chem. Soc., 1974, 91, 1371.
  12. K. W. Chiu, P. D. Savage, G. Wilkinson and D. J. Williams, Polyhedron, 1985, 4, 1941 CrossRef.
  13. M. L. Greer, H. Sarker, M. E. Medicino and S. C. Blackstock, J. Am. Chem. Soc., 1995, 117, 10 460 CrossRef CAS.
  14. D. A. Fletcher, B. G. Gowenlock, K. G. Orrell, V. [S with combining breve]ik, D. E. Hibbs, M. B. Hursthouse and K. M. A. Malik, J. Chem. Soc., Perkin Trans. 2, 1996, 191 RSC.
  15. B. Tinant, J. P. Declerq and O. Exner, Bull. Soc. Chim. Belg., 1987, 96, 149 CAS.
  16. R. Hoffman, R. Gleiter and F. B. Mallory, J. Am. Chem. Soc., 1970, 92, 1460 CrossRef CAS.
  17. T. Minato, S. Yanabe and I. Oda, Can. J. Chem., 1982, 60, 2740 CAS.
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