View PDF Version
 
DOI: 10.1039/A607544D (Paper) Reference Section for: J. Chem. Res. (S), 1997, 88-89

Nitrosation of N-Methyl-4-tolylsulfonylguanidine†

(Note: The full text of this document is currently only available in the PDF Version )

J. Ramon Leis, Fátima Norberto, José A. Moreira and Jim Iley

Abstract

Kinetic studies for the nitrosation of N-methyl-4-tolylsulfonylguanidine identify a mechanism involving rapid nitrosation of the N-methyl nitrogen atom followed by slow, general-base-catalysed proton transfer.

References

  1. G. Hallett and D. L. H. Williams, J. Chem. Soc., Perkin Trans. 2, 1980, 1371 RSC.
  2. A. Castro, E. Iglesias, J. R. Leis, M. E. Peña and J. Vazquez Tato, J. Chem. Soc., Perkin Trans. 2, 1986, 1725 RSC.
  3. J. R. Leis, M. E. Peña, M. J. Blanco and L. Garcia-Rio, J. Chem. Res. (S), 1992, 338 Search PubMed.
  4. F. Norberto, J. A. Moreira, E. Rosa, J. Iley, J. R. Leis and M. E. Peña, J. Chem. Soc., Perkin Trans. 2, 1993, 1561 RSC.
  5. E. H. White, J. Am. Chem. Soc., 1955, 77, 6008 CrossRef CAS.
  6. A. Castro, M. Mosquera, M. F. Rodriguez Prieto, J. A. Santaballa and J. Vazquez Tato, J. Chem. Soc., Perkin Trans. 2, 1988, 1963 RSC.
Click here to see how this site uses Cookies. View our privacy policy here.