Photoisomerization of 2-(Hept-6-enyl)cyclopent-12-enones
to Tricyclo[7.3.0.0]dodecan-12-ones
(Note: The full text of this document is currently only available in the PDF Version )
Rolf Christoph Gebel and Paul Margaretha
Abstract
On irradiation (λ>340 nm), the newly
synthesized 2-(hept-6-enyl)cyclopent-2-enones 1 and 2 isomerize
selectively to the straight cycloadducts
(tricyclo[7.3.0.0{???}]dodecan-12-ones) 10 and 11,
respectively.
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