Novel Preparation of 1-Aryl-3-(2-hydroxyphenyl)- 2-pyrazolin-5-ones and their Conversion into 2-Aryl- 4-methyl[1]benzopyrano[4,3-c]pyrazol-3(2H)-ones †

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Jayne A. Froggett, Michael H. Hockley and Roger B. Titman


Abstract

1-Aryl-3-(2-hydroxyphenyl)-2-pyrazolin-5-ones are prepared from 4-hydroxycoumarin and arylhydrazines and then cyclised with triethyl orthoacetate to give 2-aryl-4-methyl[1]benzopyrano[4,3-c]pyrazol-3(2H)-ones.


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