Reaction of Triazene 1-Oxides: Novel Synthesis of Solid Arenediazonium Chlorides†

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Shaaban K. Mohamed, Mohsen A.-M. Gomaa and Ahmed M. Nour El-Din


Abstract

Treatment of 1,3-diaryltriazene 1-oxides with oxalyl chloride in dry toluene at room temperature gives only solid arenediazonium chlorides; however, treatment with acetyl and benzoyl chlorides does not afford the corresponding diazonium chlorides.


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