¹⁷O and ¹H NMR chemical shifts of hydroxide and hydronium ion in aqueous solutions of strong electrolytes

Abstract

The ¹⁷O and ¹H NMR chemical shifts of water [δ(¹⁷OH₂), δ(¹H₂O)] in aqueous solutions of NaCl, NaBr, NaI, NaNO₃, NaClO₄, NaOH, KCl, KBr, KNO₃ and KOH have been measured and used to determine the δ(¹⁷O), and δ(¹H) chemical shifts of hydroxide ion and some of its aqua-complexes. The δ(¹⁷O), and δ(¹H) chemical shifts for the OH^-···nH₂O and H⁺···nH₂O complexes are discussed.

References

1. (a) V. Mäemets and I. Koppel, J. Chem. Res. (M), 1996, 2101; (b) J. Chem. Soc. Faraday Trans., 1996, 92, 3533.
2. Z. Luz and G. Yagil, J. Phys. Chem., 1966, 70, 554.
3. H. S. Gutowsky and A. Saika, J. Chem. Phys., 1953, 21, 1688.
4. J. N. Shoolery and B. J. Alder, J. Chem. Phys., 1955, 23, 805.
5. J. W. Akitt, J. Chem. Soc., Dalton Trans., 1973, 1446.
6. C. E. Taylor and C. Tomlinson, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 1132.
7. J. E. Desnoyers and J. Jolicoeur, Modern Aspects of Electrochemistry, ed. J. O'M Bockris and B. E. Conway, 1983, vol. 5, p. 1.
8. F. Fister and H. G. Hertz, Ber. Bunsen-Ges. Phys. Chem., 1967, 71, 1032.
9. J. C. Hindman, J. Chem. Phys., 1962, 36, 1000.
10. J. Davies, S. Ormondroyd and M. C. R. Symons, Trans. Faraday Soc., 1971, 67, 3465.
11. H. G. Hertz and W. Spalthoff, Z. Electrochem., 1959, 63, 1096.
12. B. P. Fabricand and S. Goldberg, J. Chem. Phys., 1961, 34, 1624.
13. J. W. Akitt, J. Chem. Soc., Dalton Trans., 1973, 42.
14. J. F. Hinton and E. S. Amis, Chem. Rev., 1971, 71, 627.
15. P. Kebarle, Annu. Rev. Phys. Chem., 1977, 28, 445 and references therein.
16. M. Tuckerman, K. Laasonen and M. Sprik, J. Chem. Phys., 1995, 103, 150.
17. A. E. Florin and M. Alei, J. Chem. Phys., 1967, 47, 4268.
18. J. C. Hindman, J. Chem. Phys., 1966, 44, 4583.