High-activity Au/CuO–ZnO catalysts for the oxidation of carbon monoxide at ambient temperature

(Note: The full text of this document is currently only available in the PDF Version )

Graham J. Hutchings, M. Rafiq H. Siddiqui, Andrew Burrows, Christopher J. Kiely and Robin Whyman


Abstract

Ambient temperature CO oxidation has been studied with Au/ZnO, Au/CuO and Au/CuO–ZnO catalysts prepared by a coprecipitation method. The catalysts are highly active for CO oxidation and are capable of sustained activity at 20°C. The highest activity is observed with Au/ZnO and this catalyst is shown, using transmission electron microscopy, to be comprised of smaller Au metal particles (2–5 nm) and a higher Au dispersion when compared with the other catalysts.


References

  1. J. J. Spivey and J. B. Butt, Catal. Today, 1991, 11, 465 CrossRef.
  2. M. Haruta, N. Yamada, T. Kobayashi and S. Iijima, J. Catal., 1989, 115, 301 CrossRef CAS.
  3. D. A. H. Cunningham, T. Kobayashi, N. Kamijo and M. Haruta, Catal. Lett., 1994, 25, 257 CrossRef CAS.
  4. F. Boccuzzi, A. Chiorino, S. Tsubota and M. Haruta, Catal. Lett., 1994, 29, 225 CrossRef CAS.
  5. M. Haruta, S. Tsubota, T. Kobayashi, H. Kageyama, M. J. Genet and B. Delmon, J. Catal., 1993, 144, 175 CrossRef CAS.
  6. S. D. Gardner, G. B. Hoflund, D. R. Schryer, J. Schryer, B. T. Upchurch and E. J. Kielen, Langmuir, 1991, 7, 2135 CrossRef CAS.
  7. S. D. Lin, M. Bollinger, M. A. Varice and Catal., Catal. Lett., 1993, 17, 245 CrossRef CAS.
  8. G. Srinivas, J. Wright, C.-S. Bai and R. Cook, Stud. Surf. Sci. Catal., 1996, 101, 427 CAS.
  9. R. W. Joyner, F. King, M. A. Thomas and G. Roberts, Catal. Today, 1991, 10, 417 CrossRef CAS.
  10. M. Haruta, A. Ueda, R. M. Torres Sanchez and K. Tanaka, Preprint Petroleum Division, ACS Symposium, American Chemical Society, New Orleans, 1996.
  11. T. Hayashi, K. Tanaka and M. Haruta, Preprint Petroleum Division, ACS Symposium, American Chemical Society, New Orleans, 1996.
Click here to see how this site uses Cookies. View our privacy policy here.