View PDF Version
 
DOI: 10.1039/A706986C (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 4477-4478

Novel binuclear copper(I) complexes with unusual azide and thiocyanate bridges. Crystal structures of [Cu2(µ-Ph2Ppypz)2(µ-1,1-N3)][ClO4]·Et2O and [Cu2(µ-Ph2Ppypz)2(µ-1,1-SCN)][ClO4] [Ph2Ppypz = 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine]

(Note: The full text of this document is currently only available in the PDF Version )

Shan-Ming Kuang, Zheng-Zhi Zhang, Qi-Guang Wang and Thomas C. W. Mak

Abstract

The first binuclear copper(I) complex with a µ-1,1-N3 bridge, [Cu2(µ-Ph2Ppypz)2(µ-1,1-N3)][ClO4]·Et2O and [Cu2(µ-Ph2Ppypz)2(µ-1,1-SCN)] [ClO4] [Ph2Ppypz = 2-(diphenylphosphino)-6-(pyrazol-1-yl)pyridine], which exhibits an unusual thiocyanate (µ-1,1-SCN) bridge, have been synthesised and characterised.

References

  1. E. I. Solomon, M. J. Baldwin and M. D. Lowery, Chem. Rev., 1992, 92, 521 CrossRef CAS; K. D. Karlin and Z. Tyeklár, Bioinorganic Chemistry of Copper, Chapman and Hall, New York, London, 1993, pp. 143–196 Search PubMed.
  2. See for example, (a) L. K. Thompson, S. S. Tandon and M. E. Manuel, Inorg. Chem., 1995, 34, 2356 CrossRef; (b) J. H. Satcher, jun., M. W. Droege, T. J. R. Weakley and R. T. Taylor, Inorg. Chem., 1995, 34, 3317 CrossRef; (c) G. A. van Albada, M. T. Lakin, N. Veldman, A. L. Spek and J. Reedijk, Inorg. Chem., 1995, 34, 4910 CrossRef CAS; (d) M.-V. Chow, Z.-Y. Zhou and T. C. W. Mak, Inorg. Chem., 1992, 31, 4900 CrossRef CAS.
  3. R. F. Ziolo, A. P. Gaughan, Z. Dori, C. G. Pierpont and R. Eisenberg, Inorg. Chem., 1971, 10, 1289 CrossRef.
  4. See for example, M. Julve, M. Verdaguer, G. De Munno, J. A. Real and G. Bruno, Inorg. Chem., 1993, 32, 795 Search PubMed; V. Kettmann, J. Kratsmar-Smogrovic, O. Svajlenova and M. Zemlicka, Z. Naturforsch., Teil B, 1992, 47, 1565 CrossRef CAS; G. De Munno, G. Bruno, F. Nicolo, M. Julve and J. A. Real, Acta Crystallogr., Sect. C, 1993, 49, 457 CAS.
  5. S. M. Nelson, F. S. Esho and M. G. B. Drew, J. Chem. Soc., Chem. Commun., 1981, 388 RSC.
  6. S.-M. Kuang, Q.-G. Wang, Z.-Z. Zhang and T. C. W. Mak, unpublished work.
  7. K. D. Karlin, B. I. Cohen, J. C. Hayes, A. Farooq and J. Zubieta, Inorg. Chem., 1987, 26, 147 CrossRef CAS.
  8. M. A. S. Goher and T. C. W. Mak, Inorg. Chim. Acta, 1985, 99, 223 CrossRef CAS.
  9. T. C. W. Mak and M. A. S. Goher, Inorg. Chim. Acta, 1986, 115, 17 CrossRef CAS.
  10. M. Melnik, L. Macaskova and C. E. Holloway, Coord. Chem. Rev., 1993, 126, 71 CrossRef CAS.
  11. A. T. Baker, D. C. Craig and G. Dong, Inorg. Chem., 1996, 35, 1091 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.