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DOI: 10.1039/A705120D (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 4139-4142

Novel syntheses of linked cyclopentadienyl–amide complexes

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Andrew K. Hughes and Andrew J. Kingsley

Abstract

The reaction of C5H5CH2CH2CH2NHMe with [W(NBut)2(NHBut)2] proceeded in a two-step fashion to give the formally 22-electron complex [W(NBut)2(η5,σ-C5H4CH2CH2CH2NMe)]; the reaction of Li2[C5H4CH2CH2CH2NMe] with [Mo(NBut)2Cl2(dme)] (dme = 1,2-dimethoxyethane) or [Zr(η-C5H5)2Cl2] gave [Mo(NBut)2(η5,σ-C5H4CH2CH2CH2NMe)] or [Zr(η-C5H5)Cl(η5∶σ-C5H4CH2CH2CH2NMe)] respectively.

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