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DOI: 10.1039/A704997H (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 3081-3082

Neutron diffraction study of the ‘elongated’ molecular dihydrogen complex [(C5Me5)Os(H2)H2(PPh3 )]+[hair space]

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Christopher L. Gross, Dianna M. Young, Arthur J. Schultz and Gregory S. Girolami

Abstract

Protonation of the osmium(IV) hydrides (C5Me5)OsH3(L) with HBF4 in diethyl ether afforded the cationic dihydrogen complexes [(C5Me5)Os(H2)H2(L)][BF 4], where L is PPh3 1 or AsPh3 2; a single-crystal neutron diffraction study of 1 reveals that the H–H distance is 1.014(11) Å.

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