Overcrowding leads to prism reform: new polyhedra for polymetallic cages

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Euan K. Brechin, Alasdair Graham, Steven G. Harris, Simon Parsons and Richard E. P. Winpenny


Abstract

The synthesis and crystal structure of new deca- and octa-nuclear cages featuring the ligands 6-methyl-2-pyridonate and trimethylacetate (OCCMe3) have been determined; the structures involve polyhedra based on a tetraicosahedron and a cube respectively.


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