View PDF Version
 
DOI: 10.1039/A704511E (Paper) Reference Section for: J. Chem. Soc., Dalton Trans., 1997, 3705-3712

Synthesis and characterisation of tin(II) and tin(IV) citrates

(Note: The full text of this document is currently only available in the PDF Version )

Paul R. Deacon, Mary F. Mahon, Kieran C. Molloy and Phillip C. Waterfield

Abstract

A series of tin(II) citrates, SnM(C6H4O7) (M = Sn or Zn) and SnMM′(C6H4O7) (M = M′ = Na, K or NH4; M = NMe4, M′ = H) and related monotin(II) salts of 1,5-dimethyl and 1,5-di-n-butyl citrate have been synthesized and characterised by spectroscopic methods (IR, 1H, 13C, 119Sn NMR, 119Sn Mössbauer). The crystal structures of dimeric tin(II) 1,5-dimethyl citrate and an oxidation product, Sn(NMe4)2(C6H5O7)2·3.5H2O, have also been determined.

References

  1. L. Stryer, Biochemistry, W. H. Freeman and Co., New York, 4th edn., 1995, p. 509 Search PubMed .
  2. P. J. Sadler and H. Sun, J. Chem. Soc., Dalton Trans., 1995, 1395 RSC .
  3. G. Smith, D. S. Sagatys, R. C. Bott and D. E. Lynch, Polyhedron, 1993, 12, 1491 CrossRef CAS .
  4. D. E. Zacharias and J. P. Glusker, Acta Crystallogr., Sect. C, 1993, 49, 1727 CrossRef .
  5. A. A. Sheikh-Osman, R. Bertani, A. Tapparo, G. G. Bombi and B. Corain, J. Chem. Soc., Dalton Trans., 1993, 3229 RSC .
  6. D. S. Sagatys, G. Smith, R. C. Bott and D. E. Lynch, Polyhedron, 1993, 12, 709 CrossRef CAS .
  7. J. C. Sherlock and S. C. Britton, Br. Corros. J., 1972, 7, 180 Search PubMed .
  8. A. R. Willey, Br. Corros. J., 1972, 7, 29 Search PubMed .
  9. D. W. Gruenwedel and H.-S. Hao, J. Agr. Food Chem., 1973, 21, 246 CrossRef CAS .
  10. G. Arena, A. Contino, S. Musumeci and R. Purrello, J. Chem. Soc., Dalton Trans., 1990, 3383 RSC .
  11. M. M. Besso, US Pat., 3 213 120, 1965 Search PubMed .
  12. T. D. Smith, J. Chem. Soc., 1965, 2145 RSC .
  13. V. I. Korsunsky, P. G. Antonov and T. P. Lutsko, Polyhedron, 1992, 11, 1403 CrossRef .
  14. N. Tinanoff, J. Clin. Dentistry, 1990, 2, 22 Search PubMed .
  15. G. Schroeter and L. Shultz, Ber. Deutsch. Chem. Ges., 1902, 35, 2085 Search PubMed .
  16. M. J. Milewska, A. Chimiak and Z. Glowacki, J. Prakt. Chem., 1987, 329, 447 CrossRef CAS .
  17. R. Gsell and M. Zeldin, J. Inorg. Nucl. Chem., 1975, 37, 1133 CrossRef CAS .
  18. P. G. Harrison, B. J. Haylett and T. J. King, J. Chem. Soc., Chem. Commun., 1978, 112 RSC .
  19. D. W. Hartley, G. Smith, D. S. Sagatys and C. H. L. Kennard, J. Chem. Soc., Dalton Trans., 1991, 2735 RSC .
  20. T. Fjeldberg, P. B. Hitchcock, M. F. Lappert, S. J. Smith and A. J. Thorne, J. Chem. Soc., Chem. Commun., 1985, 939 RSC .
  21. P. G. Harrison and E. W. Thornton, J. Chem. Soc., Dalton Trans., 1978, 1274 RSC .
  22. N. W. Alcock and S. M. Roe, J. Chem. Soc., Dalton Trans., 1989, 1589 RSC .
  23. H. Reuter and D. Schroder, Acta Crystallogr., Sect. C, 1992, 48, 1112 CrossRef .
  24. H. L. Carrell and J. P. Glusker, Acta Crystallogr., Sect. B, 1973, 29, 638 CrossRef CAS .
  25. C. K. Johnson, Acta Crystallogr., 1965, 18, 1004 CrossRef CAS .
  26. T. Birchall and J. P. Johnson, Inorg. Chem., 1982, 21, 3724 CrossRef CAS .
  27. J. D. Donaldson and A. Jelen, J. Chem. Soc. A, 1968, 1448 RSC .
  28. W. D. Honnick and J. J. Zuckerman, Inorg. Chem., 1978, 17, 501 CrossRef CAS .
  29. S. Tsuji, T. Shibata, Y. Ito, S. Fujii and K. Tomita, Acta Crystallogr., Sect. C, 1991, 47, 528 CrossRef .
  30. K. C. Molloy, T. G. Purcell, K. Quill and I. W. Nowell, J. Organomet. Chem., 1984, 267, 237 CrossRef CAS .
  31. U. S. Pharmacopeia, The US Pharmacopeial Convention, Inc., Rockville, MD, Assay for Stanous Ion, 1990, USP XXII, 1274 .
  32. N. Walker and D. Stewart, Acta Crystallogr., Sect. A, 1983, 39, 158 CrossRef .
  33. G. M. Sheldrick, SHELX 76, A program for crystal structure determination, University of Cambridge, 1976 .
  34. G. M. Sheldrick, SHELXS 86, A program for crystal structure determination, University of Göttingen, 1986 .
Click here to see how this site uses Cookies. View our privacy policy here.